NaB3O4F(OH): A Hydroxyfluorooxoborate with One-Dimensional Chain Featuring Large Birefringence and Short Ultraviolet Cutoff Edge.
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DOI: 10.1021/acs.inorgchem.2c02379
Abstract: A new sodium hydroxyfluorooxoborate, NaB3O4F(OH) (NBOFH), was discovered and synthesized. NBOFH features the unprecedented [B3O4F(OH)] infinite chain constructed by the novel fundamental building block (FBB) of [B3O5F(OH)]. NBOFH has a large birefringence of 0.097 at… read more here.
Keywords: large birefringence; ultraviolet cutoff; short ultraviolet; cutoff edge ... See more keywords
BaB2P2O8F2: A Fluoroborophosphate with [B2P2O8F2]∞ Layers and Deep-Ultraviolet Cutoff Edge.
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DOI: 10.1021/acs.inorgchem.2c03915
Abstract: A fluoroborophosphate, BaB2P2O8F2, was successfully obtained. Its structure contains a novel [B2P2O8F2]∞ layer containing six-membered rings, which is formed by the fundamental building block composed of three types of non-π-conjugated groups, [PO4], [BO4], and [BO2F2].… read more here.
Keywords: bab2p2o8f2; cutoff edge; fluoroborophosphate; deep ultraviolet ... See more keywords
A Member of Fluorooxoborates: Li2Na0.9K0.1B5O8F2 with the Fundamental Building Block B5O10F2 and a Short Cutoff Edge.
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DOI: 10.1021/acs.inorgchem.7b02838
Abstract: A new member of fluorooxoborates, Li2Na0.9K0.1B5O8F2, was obtained in the sealed system, and single-crystal X-ray diffraction was used to determine its structure. It contains a three-dimensional framework stacking of [B5O8F2]3- layers extending into the ac… read more here.
Keywords: li2na0 9k0; cutoff edge; fundamental building; member fluorooxoborates ... See more keywords