Copper-Catalyzed Enantioselective Decarboxylative Cyanation of Benzylic Acids Promoted by Hypervalent Iodine(III) Reagents.
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DOI: 10.1021/acs.orglett.3c00816
Abstract: Copper-catalyzed asymmetric radical cyanation reactions have emerged as a powerful strategy for rapid construction of α-chiral nitriles. However, the directly decarboxylative cyanation reactions of common alkyl carboxylic acids remain largely elusive. Herein, we report a… read more here.
Keywords: enantioselective decarboxylative; benzylic acids; cyanation; cyanation benzylic ... See more keywords