Total Syntheses of 2,2′-Biindolyl Alkaloids via Cyanide-Catalyzed Imino-Stetter Reaction
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DOI: 10.1055/a-2069-3913
Abstract: 2,2’-Biindolyl natural products have a long history of applications owing to their unique structural features and biological activities. In this account, we describe the recent progress achieved by our research group in the total syntheses… read more here.
Keywords: stetter reaction; imino stetter; reaction; catalyzed imino ... See more keywords
Concise Total Syntheses of Paullone and Kenpaullone via Cyanide-Catalyzed Intramolecular Imino-Stetter Reaction
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DOI: 10.1055/s-0036-1588749
Abstract: Highly concise total syntheses of paullone and kenpaullone were developed. Cyanide-catalyzed intramolecular imino-Stetter reaction of aldimines derived from methyl 2-aminocinnamate derivatives and 2-nitrobenzaldehyde provided 2-(2′-nitrophenyl)indole-3-acetic acid derivatives. Subsequent reduction of the nitro group with zinc… read more here.
Keywords: total syntheses; concise total; cyanide catalyzed; paullone kenpaullone ... See more keywords