An Azido-Cyanide Mixed-Bridged [Fe4Ni4] Single-Molecule Magnet.
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DOI: 10.1021/acs.inorgchem.8b03559
Abstract: Taking advantages of both azide and cyanide bridges in magnetism and synthesis, an azido-cyanide mixed-bridged octanuclear [FeIII4NiII4] SMM of [{(enbzpy)Ni2(μ1,1-N3)2·(DMF)}{Tp*Fe(CN)3}2]2·2DMF·14H2O (1) was explored and characterized, which exhibits slow relaxation of the magnetization and an S… read more here.
Keywords: cyanide mixed; mixed bridged; azido; bridged fe4ni4 ... See more keywords