Cyanido‐Bridged FeII–MI Dimetallic Hofmann‐Like Spin‐Crossover Coordination Polymers Based on 2,6‐Naphthyridine
Sign Up to like & getrecommendations! Published in 2018 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700920
Abstract: Two new 3D spin crossover (SCO) Hofmann-type coordination polymers {Fe(2,6-naphthy)[Ag(CN)2][Ag2(CN)3]} (1) and {Fe(2,6-naphthy)[Au(CN)2]2}·(0,5)PhNO2 (2) (2,6-naphthy = 2,6-naphthyridine) have been synthesized and characterized. Both derivatives are made up of infinite stacks of {Fe[Ag(CN)2]2[Ag2(CN)3]}n and {Fe[Au(CN)2]2}n layered… read more here.
Keywords: feii dimetallic; bridged feii; spin crossover; coordination polymers ... See more keywords
Dual Emission in the Near-Infrared and Visible Regions from a Mixed Cyanido-Bridged EuIII/NdIII(4-OHpy)-CoIII Layered Material
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c01988
Abstract: Coordination polymers (CPs) with a dual emission spanning from the visible (vis) to near-infrared (NIR) regions of the electromagnetic spectrum are used for optical sensors, medical diagnostics, and telecommunication technologies. We herein report the synthesis,… read more here.
Keywords: cyanido bridged; dual emission; near infrared; emission ... See more keywords
Irradiation Temperature Dependence of the Photomagnetic Mechanisms in a Cyanido-Bridged CuII2MoIV Trinuclear Molecule.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b00545
Abstract: We report a new bimetallic cyanido-bridged trinuclear complex [CuII(enpnen)]2[MoIV(CN)8]·6.75H2O (1) (enpnen = N,N'-bis(2-aminoethyl)-1,3-propanediamine) that shows reversible photomagnetic effect. The photo-induced increase of magnetization is characterized by the irradiation temperature-dependent shapes of the χM T( T)… read more here.
Keywords: temperature; effect; irradiation temperature; cuii ... See more keywords
Europium(III) Photoluminescence Governed by d8-d10 Heterometallophilic Interactions in Trimetallic Cyanido-Bridged Coordination Frameworks.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b03114
Abstract: We report an efficient pathway toward sensitization of red room temperature EuIII emission by the charge-transfer (CT) states related to d8-d10 heterometallophilic interactions achieved by the simultaneous application of tetracyanidometallates of PtII/PdII and dicyanidometallates of… read more here.
Keywords: coordination; heterometallophilic interactions; metal; d10 heterometallophilic ... See more keywords
Dehydration-Hydration Switching of Single-Molecule Magnet Behavior and Visible Photoluminescence in a Cyanido-Bridged DyIIICoIII Framework.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b09103
Abstract: Microporous magnets compose a class of multifunctional molecule-based materials where desolvation-driven structural transformation leads to the switching of magnetic properties. Herein, we present a special type of microporous magnet where dehydration-hydration process within bimetal coordination… read more here.
Keywords: geometry; single molecule; dyiii; cyanido bridged ... See more keywords
A two-fold 3D interpenetrating cyanido-bridged network based on the octa-coordinated [Mo(CN)8]4− building block
Sign Up to like & getrecommendations! Published in 2019 at "CrystEngComm"
DOI: 10.1039/c9ce00851a
Abstract: By varying the reaction conditions, three CN-bridged coordination polymers of different dimensionalities and topologies are obtained from the same building blocks. read more here.
Keywords: network based; cyanido bridged; two fold; fold interpenetrating ... See more keywords
Investigation of the electron transfer properties between metal centers in binuclear and trinuclear cyanido-bridged mixed valence complexes with cis/trans-configuration.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01313d
Abstract: To investigate the electron transfer properties between metal centers and their influencing factors in binuclear and trinuclear cyanido-bridged mixed valence complexes with cis/trans-configuration, binuclear cis-[Cp(dppe)Fe(μ-NC)Ru(5,5'-dmbpy)2(μ-CN)][PF6]n (cis-1[PF6]n, n = 1, 2) and trinuclear cis/trans-[Cp(dppe)Fe(μ-NC)Ru(5,5'-dmbpy)2(μ-CN)Fe(dppe)Cp][PF6]n (cis/trans-2[PF6]n, n… read more here.
Keywords: valence complexes; cyanido bridged; cis; mixed valence ... See more keywords
A Cyanido-bridged Luminescent Coordination Polymer Composed of Janus-type Layers and Its Two-dimensional Negative Thermal Expansion
Sign Up to like & getrecommendations! Published in 2021 at "Chemistry Letters"
DOI: 10.1246/cl.210244
Abstract: A luminescent two-dimensional coordination polymer of type [Cd(H2O)(EtOH)][ReN(CN)4(H2O)]·2H2O (CdRe) incorporating “Janus-type” cyanido-bridged layers was synthesized. Within each layer of CdRe, t... read more here.
Keywords: cyanido bridged; type; coordination polymer; janus type ... See more keywords