Cd(II)/Fe(III) heterobimetallic complexes with dien and cyanido ligands as precursors of ferrite-type oxides: Syntheses, crystal structures, thermal properties and identification of the oxides
Sign Up to like & getrecommendations! Published in 2021 at "Polyhedron"
DOI: 10.1016/j.poly.2021.115101
Abstract: Abstract From the aqueous systems Cd(II) – dien – [Fe(CN)6]3-, where dien is 1,4,7-triazaheptane, two novel ionic complexes [Cd(dien)2]3[Fe(CN)6]2.3H2O (1) and NH4[Bu4N][Cd(dien)2]2[Fe(CN)6]2 (2) were prepared and characterized by spectroscopic (IR and UV-VIS) and EDX method.… read more here.
Keywords: cyanido ligands; crystal structures; complexes dien; heterobimetallic complexes ... See more keywords
Non-innocent cyanido ligands: tetracyanidoferrate(-II) as carbonyl copycat.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00833e
Abstract: While a negative oxidation state occurs rarely for metals in general, this is commonly known for metal carbonyl anions, i.e. carbonyl metalates. Although CO and CN- are isoelectronic, cyanidometalates usually do not exhibit metal centers… read more here.
Keywords: cyanido ligands; ligands tetracyanidoferrate; carbonyl copycat; tetracyanidoferrate carbonyl ... See more keywords