Co–Co and Co–Fe cyano-bridged pentanuclear clusters based on a methylpyrazinyl-diamine tetradentate ligand: spin crossover and metal substitution effects
Sign Up to like & getrecommendations! Published in 2017 at "CrystEngComm"
DOI: 10.1039/c7ce01826f
Abstract: A pentanuclear CoII–CoIII cluster complex has been developed by a solvothermal synthesis. Its highly stable metal-mixed iron–cobalt derivatives display robust spin crossover (T1/2 = 268 K) controlled by the degree of substitution. read more here.
Keywords: metal; cyano bridged; spin crossover; substitution ... See more keywords
Charge transfer and slow magnetic relaxation in a series of cyano-bridged FeIII4MII2 (M = FeII, CoII, NiII) molecules
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic Chemistry Frontiers"
DOI: 10.1039/c8qi01245h
Abstract: The synthesis, single-crystal structures and magnetic properties of three new cyano-bridged complexes [FeIII4MII2] (M = FeII, CoII, NiII) are reported. read more here.
Keywords: feiii4mii2 feii; coii niii; cyano bridged; feii coii ... See more keywords
H/F Substitution induced switchable coordination bonds in a cyano-bridged hybrid double perovskite ferroelastic.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00586g
Abstract: A three-dimensional cyano-bridged double perovskite ferroelastic [(CH3)3NCH2F]2[KFe(CN)6] was constructed by introducing unprecedented switchable C-F-K coordination bonds. H/F substitution not only preserves the basic structure of the parent [(CH3)4N]2[KFe(CN)6] but also affords an m3̄mF2/m-type ferroelastic phase… read more here.
Keywords: perovskite ferroelastic; cyano bridged; switchable coordination; coordination bonds ... See more keywords
Intrinsic Multienzyme-like Activities of the Nanoparticles of Mn and Fe Cyano-Bridged Assemblies
Sign Up to like & getrecommendations! Published in 2022 at "Nanomaterials"
DOI: 10.3390/nano12122095
Abstract: This study investigates the intrinsic multienzyme-like properties of the non-stabilized nanocrystalline nanoparticles of manganese-doped Prussian blue (Mn-PB) nanozymes and Prussian blue (PB) nanozymes in chemical and electrocatalytic transformations of reactive oxygen species. The effect of… read more here.
Keywords: multienzyme like; like activities; intrinsic multienzyme; cyano bridged ... See more keywords