Transition-metal free cyano 1,3 migration of unsaturated cyanohydrins
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DOI: 10.1039/d1qo00181g
Abstract: A novel approach of transition-metal-free cyano 1,3-migration of β,γ- and α,β-unsaturated cyanohydrins is reported. read more here.
Keywords: transition metal; migration unsaturated; unsaturated cyanohydrins; metal free ... See more keywords
Organocatalytic radical relay trifunctionalization of unactivated alkenes by a combination of cyano migration and alkylacylation.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc01625k
Abstract: The first N-heterocyclic carbene organocatalytic three-component radical relay trifunctionalization of unactivated alkenes through the combination of remote 1,4-cyano migration and alkylacylation was reported. This protocol features mild reaction conditions, readily available materials, excellent regioselectivity, and… read more here.
Keywords: alkenes combination; relay trifunctionalization; radical relay; cyano migration ... See more keywords