Phosphinoyl Radical Initiated Vicinal Cyanophosphinoylation of Alkenes.
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DOI: 10.1021/acs.orglett.7b02621
Abstract: A double-functionalization reaction of alkenes through Mn(OAc)3-mediated phosphinoyl radical addition followed by CuCN-catalyzed cyanation is introduced. This one-pot reaction is performed under mild conditions to afford vicinal cyanophosphinoylation products. read more here.
Keywords: vicinal cyanophosphinoylation; cyanophosphinoylation alkenes; radical initiated; phosphinoyl radical ... See more keywords