A Highly Porous Co-MOF for Cyanosilylation Reaction and Inhibition on P. gingivalis Growth and rgp and kgp Expression for Periodontal Treatment
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Cluster Science"
DOI: 10.1007/s10876-019-01714-5
Abstract: A novel porous three-dimensional Co(II) organic framework of metal, [{Co2(TCPP)(H2O)}·DMF]n (1), (where H4TCPP = 2,3,5,6-tetrakis(4-carboxyphenyl)pyrazine) was synthesized under the solvent thermal condition, consisting of a H4TCPP ligand which is rigid and tetratopic. Intriguingly, the centers of Co(II)… read more here.
Keywords: cyanosilylation; expression; porous mof; highly porous ... See more keywords
2D Hybrid Architectures Constructed from Two Kinds of Polyoxovanadates as Efficient Heterogeneous Catalysts for Cyanosilylation and Knoevenagel Condensation.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c00999
Abstract: The design of heterogeneous catalysts for highly efficient catalysis for cyanosilylation reactions and Knoevenagel condensations is greatly significant, due to the important application of their products in industry. Herein, five hybrid compounds constructed from two… read more here.
Keywords: cyanosilylation; heterogeneous catalysts; constructed two; h2o ... See more keywords
A Sacrificial Iminato Ligand in the Catalytic Cyanosilylation of Ketones Promoted by Organoactinide Complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03646
Abstract: Four new complexes containing the bis(pentamethylcyclopentadienyl)thorium(IV) moiety, Cp*2Th(L1)(Me) (Th2), Cp*2Th(L2)(Me) (Th3), Cp*2Th(L1)Cl (Th5), and Cp*2Th(L2)Cl (Th6), were synthesized in quantitative yields via the protonolysis reaction of the metallocene precursor complexes Cp*2Th(Me)2 (Th1) and Cp*2Th(Me)Cl (Th4)… read more here.
Keywords: iminato ligand; ligand catalytic; sacrificial iminato; catalytic cyanosilylation ... See more keywords
Nanosized Ti-Based Perovskite Oxides as Acid–Base Bifunctional Catalysts for Cyanosilylation of Carbonyl Compounds
Sign Up to like & getrecommendations! Published in 2023 at "ACS Applied Materials & Interfaces"
DOI: 10.1021/acsami.3c01629
Abstract: The development of effective solid acid–base bifunctional catalysts remains a challenge because of the difficulty associated with designing and controlling their active sites. In the present study, highly pure perovskite oxide nanoparticles with d0-transition-metal cations… read more here.
Keywords: base bifunctional; acid base; carbonyl compounds; bifunctional catalysts ... See more keywords
Donor free stibenium cation as an efficient cyanosilylation catalyst.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc03158b
Abstract: The synthesis of novel stibenium cations and their catalytic application in cyanosilylation of carbonyl compounds have been described. Treatment of chlorostibine L1SbCl [L1 = 1,2-C6H4{N(CH2tBu)}2] (2) with 1 equiv. of AgOTf and AgSbF6 resulted in… read more here.
Keywords: cation efficient; free stibenium; cyanosilylation; donor free ... See more keywords