Lanthanide metal organic frameworks based on dicarboxyl-functionalized arylhydrazone of barbituric acid: syntheses, structures, luminescence and catalytic cyanosilylation of aldehydes.
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DOI: 10.1039/c7dt01056g
Abstract: Five isostructural lanthanide MOFs, [Ln(1κOO',2κO'',3κO''',4κO''''-μ4-L)(NO3)(DMF)2]n·n(DMF) {Ln = La3+ (1), Ce3+ (2), Nd3+ (3), Sm3+ (4) and Dy3+ (5); L = 5-[2-{2,4,6-trioxotetrahydropyrimidin-5(2H)-ylidene}hydrazinyl]isophthalate; DMF = N,N'-dimethyl formamide}, based on dicarboxyl-functionalized arylhydrazone of barbituric acid were synthesized under… read more here.
Keywords: based dicarboxyl; arylhydrazone barbituric; barbituric acid; cyanosilylation aldehydes ... See more keywords
Cyanosilylation of aldehydes catalyzed by a porous metal-organic framework containing a coordinatively unsaturated Zn(II) center and its anticancer activity in human osteogenic sarcoma
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DOI: 10.1080/00958972.2019.1659963
Abstract: Abstract Solvothermal reaction of Zn(NO3) · 6H2O with the tripodal ligand 1,3,5-tris(4-carboxyphenyl)benzene (H3BTB) afforded a highly porous metal-organic framework (MOF) {[Zn3(BTB)2(H2O)2] · 7DMF}n (1). The resulting activated 1a exhibits BET surface areas of 1021 m2 g−1… read more here.
Keywords: porous metal; cyanosilylation aldehydes; metal organic; anticancer activity ... See more keywords