Formation of Heteropolynuclear Lanthanide Complexes Using Macrocyclic Phosphonated Cyclam-Based Ligands.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c01456
Abstract: Ligands L1 and L2, respectively based on a cyclam and a cross-bridged cyclam scaffold functionalized at N1 and N8 by 6-phosphonic-2-methylene pyridyl groups, are described. While complexation of lanthanide (Ln) cations with L2 was not… read more here.
Keywords: cyclam; lanthanide complexes; formation; formation heteropolynuclear ... See more keywords
Thermostructural Behavior in a Series of Lanthanide-Containing Polyoxotungstate Hybrids with Copper(II) Complexes of the Tetraazamacrocycle Cyclam: A Single-Crystal-to-Single-Crystal Transformation Study.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b03471
Abstract: A series of 14 isostructural [Cu(cyclam)]2[{Cu(cyclam)}4{(α-GeW11O39)Ln(H2O)(OAc)}2]·18H2O (1-Ln, where Ln = La-Lu; cyclam = 1,4,8,11-tetraazacyclotetradecane) polyoxometalate-based hybrids reported herein represent (i) the first example of a two-dimensional covalent hybrid lattice involving the [{(α-XW11O39)Ln(H2O)(OAc)}2] n- archetype and… read more here.
Keywords: crystal single; cyclam; single crystal; thermostructural behavior ... See more keywords
Equatorial restriction of the photoinduced Jahn-Teller switch in Mn(III)-cyclam complexes
Sign Up to like & getrecommendations! Published in 2023 at "Chemical Science"
DOI: 10.1039/d3sc01506h
Abstract: Ultrafast transient absorption spectra were recorded for solutions of [MnIII(cyclam)(H2O)(OTf)][OTf]2 (cyclam = 1,4,8,11-tetraazacyclotetradecane and OTf = Trifluoromethanesulfonate) in water to explore the possibility to restrict the equatorial expansion following photoexcitation... read more here.
Keywords: cyclam; photoinduced jahn; equatorial restriction; restriction photoinduced ... See more keywords
Synthesis and crystal structure of poly[[di-μ3-tetrathioantimonato-tris[(cyclam)cobalt(II)]] acetonitrile disolvate dihydrate] (cyclam = 1,4,8,11-tetraazacyclotetradecane)
Sign Up to like & getrecommendations! Published in 2022 at "Acta Crystallographica Section E: Crystallographic Communications"
DOI: 10.1107/s2056989022001074
Abstract: In the crystal structure of the title compound, the [SbS4]3− anions are linked by the Co(cyclam) complex cations into rings, which are further connected into layers that are linked by intermolecular hydrogen bonding via the… read more here.
Keywords: poly tetrathioantimonato; synthesis crystal; cyclam; structure poly ... See more keywords
Modification of Structure and Magnetic Properties in Coordination Assemblies Based on [Cu(cyclam)]2+ and [W(CN)8]3−
Sign Up to like & getrecommendations! Published in 2019 at "Crystals"
DOI: 10.3390/cryst9010045
Abstract: The 1D {[CuII(cyclam)]3[WV(CN)8]2.5H2O}n (1·5H2O) (cyclam = 1,4,8,11-tetraazacyclotetradecane) coordination polymer of ladder topology can be obtained in water-alcohol solution from [Cu(cyclam)]2+ and [W(CN)8]3− building blocks. Upon dehydration, 1·5H2O undergoes a single-crystal-to-single-crystal structural transformation to the anhydrous… read more here.
Keywords: cyclam; coordination; cuii cyclam; topology ... See more keywords
Toward Advanced Functional Systems: Honeycomb-Like Polymeric Surfaces Incorporating Polyoxovanadates with Surface-Appended Copper-Cyclam Complexes
Sign Up to like & getrecommendations! Published in 2019 at "Molecules"
DOI: 10.3390/molecules24122313
Abstract: In this work the immobilization of hybrid polyoxometalates (POMs) onto functional polymeric surfaces is exposed and discussed. Thus, various hybrid polymer‒inorganic films were prepared by anchoring selected hybrid POMs onto tailored polymeric surfaces that consisted… read more here.
Keywords: systems honeycomb; advanced functional; cyclam; functional systems ... See more keywords