Photoinduced Ligand-to-Metal Charge Transfer (LMCT) of Fe Alkoxide Enabled C-C Bond Cleavage and Amination of Unstrained Cyclic Alcohols.
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DOI: 10.1021/acs.orglett.1c04365
Abstract: We report an alkoxy radical process for the C-C bond cleavage and functionalization of unstrained tertiary and secondary cyclic alcohols. In the absence of a chlorine atom, the readily available iron catalysts [Fe(OBu-t)3 or Fe(acac)3/t-BuONa]… read more here.
Keywords: ligand metal; bond cleavage; cyclic alcohols; transfer ... See more keywords