Current Standing on Radical Ring-Opening Polymerisations of Cyclic Ketene Acetals as Homopolymers and Copolymers with one Another.
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DOI: 10.1002/marc.202200941
Abstract: Radical Ring-opening polymerisation (RROP) of cyclic ketene acetals (CKAs) emerges to be a valuable polymerisation technique. In attracting more attention, RROP has seen a new spike in publications, which we will put into perspective. This… read more here.
Keywords: homopolymers copolymers; cyclic ketene; radical ring; ketene acetals ... See more keywords
Dithiocarbamate-mediated controlled copolymerization of ethylene with cyclic ketene acetals towards polyethylene-based degradable copolymers
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DOI: 10.1039/d0py00200c
Abstract: In this article, degradable polyethylene (PE)-based copolymers containing ester units in the backbone were prepared through the hybrid copolymerization of ethylene and cyclic ketene acetals (CKAs) mediated by dithiocarbamate successfully. read more here.
Keywords: copolymerization ethylene; polyethylene based; ethylene cyclic; ketene acetals ... See more keywords
Synthesis of degradable and chemically recyclable polymers using 4,4-disubstituted five-membered cyclic ketene hemiacetal ester (CKHE) monomers
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DOI: 10.1039/d1sc03560f
Abstract: Novel degradable and chemically recyclable polymers were synthesized using five-membered cyclic ketene hemiacetal ester (CKHE) monomers. The studied monomers were 4,4-dimethyl-2-methylene-1,3-dioxolan-5-one (DMDL) and 5-methyl-2-methylene-5-phenyl-1,3-dioxolan-4-one (PhDL). The two monomers were synthesized in high yields (80–90%), which… read more here.
Keywords: recyclable polymers; membered cyclic; chemically recyclable; degradable chemically ... See more keywords