Functional Nanoassemblies of Cyclic Polymers Show Amplified Responsiveness and Enhanced Protein-Binding Ability.
Sign Up to like & getrecommendations! Published in 2020 at "ACS nano"
DOI: 10.1021/acsnano.0c03239
Abstract: The physicochemical properties of cyclic polymer adsorbates are significantly influenced by the steric and conformational constraints introduced during their cyclization. These translate into a marked difference in interfacial properties between cyclic polymers and their linear… read more here.
Keywords: amplified responsiveness; cyclic polymers; protein binding; binding ability ... See more keywords
A Rational Entry to Cyclic Polymers via Selective Cyclization by Self-Assembly and Topology Transformation of Linear Polymers.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b01151
Abstract: A simple and effective synthetic route to cyclic polymers has been developed based on the following sequence: (i) selective cyclization of two self-complementary sec-ammonium-containing crown ether monomers to afford [c2] daisy-chain bifunctional initiators, (ii) living… read more here.
Keywords: selective cyclization; cyclic polymers; linear polymers; topology ... See more keywords
Synthesis of conjugated segment-based cyclic polymers for direct imaging of the cyclic molecular topology.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc07223d
Abstract: Conjugated polyacetylene-based monocyclic and bicyclic polymers were synthesized by blocking-cyclization metathesis polymerization using short ladderphanes as the initial motif and multi-cyclizing unit, and fully characterized to elucidate the cyclic characteristics and good photoelectric properties. Importantly,… read more here.
Keywords: topology; cyclic polymers; segment based; synthesis conjugated ... See more keywords