Iron-Catalyzed Aerobic Dehydrogenative Kinetic Resolution of Cyclic Secondary Amines.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b00615
Abstract: A nonenzymatic iron-catalyzed dehydrogenative kinetic resolution of cyclic secondary amines using air as an oxidant has been reported. The economical and practical method is applicable to a series of cyclic benzylic amines, including 5,6-dihydrophenanthridines and… read more here.
Keywords: cyclic secondary; resolution cyclic; dehydrogenative kinetic; kinetic resolution ... See more keywords
Expedient Ni(OTf)2/visible light photoredox-catalyzed annulation of donor-acceptor cyclopropanes with cyclic secondary amines.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc02941c
Abstract: The annulative coupling of donor-acceptor cyclopropanes with cyclic secondary amines is reported using the combination of Ni(OTf)2 and visible light assisted eosin Y catalysis for tandem C-N and C-C bond formation. The reaction sequence provides… read more here.
Keywords: acceptor cyclopropanes; secondary amines; donor acceptor; cyclopropanes cyclic ... See more keywords