A Highly Regioselective Palladium‐Catalyzed O,S Rearrangement of Cyclic Thiocarbonates
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DOI: 10.1002/ejoc.201701181
Abstract: This work describes an operationally simple catalytic synthesis of cyclic S-thiocarbonates with predictable regioselectivity in good yields. The reaction utilizes substrates derived from ubiquitous 1,2-diols in an atom economical intramolecular rearrangement, catalysed by an inexpensive… read more here.
Keywords: cyclic thiocarbonates; catalyzed rearrangement; regioselective palladium; palladium catalyzed ... See more keywords