Gold-Catalyzed Cyclization/Hydroboration of 1,6-Enynes: Synthesis of Bicyclo[3.1.0]hexane Boranes.
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DOI: 10.1021/acs.orglett.2c03812
Abstract: The gold-catalyzed cyclization/hydroboration of 1,6-enynes offers facile, versatile, and atom-economical one-step access to bicyclo[3.1.0]hexane boranes. This new protocol proceeds in moderate to good yields under mild conditions. Different from bicyclo[3.1.0]hexane borates, these products are stable… read more here.
Keywords: cyclization hydroboration; catalyzed cyclization; bicyclo hexane; gold catalyzed ... See more keywords