Silver-Catalyzed Carboxylative Cyclization of Primary Propargyl Alcohols with CO2.
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DOI: 10.1021/acs.orglett.9b00156
Abstract: By using silver complexes with bulky ligands such as DavePhos or N-heterocyclic carbenes, propargylic alcohols are smoothly converted with CO2 into a unique class of unexplored cyclic alkylidene carbonates. These systems, for the first time,… read more here.
Keywords: silver catalyzed; carboxylative cyclization; cyclization primary; primary propargyl ... See more keywords