Dearomative Cyclization/Spirocyclization via Electrochemical Reductive Hydroarylation of Nonactivated Arenes.
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DOI: 10.1021/acs.orglett.4c02862
Abstract: An electrochemical cyclization/spirocyclization hydroarylation via reductive dearomatization of a series of nonactivated arenes including N-substituted indoles, indole-3-carboxamide derivatives, and iodo-substituted benzamides is described. This protocol boasts high atom efficiency, broad substrate applicability, and excellent selectivity.… read more here.
Keywords: cyclization spirocyclization; dearomative cyclization; hydroarylation; nonactivated arenes ... See more keywords