A dual biomimetic process for the selective aerobic oxidative coupling of primary amines using pyrogallol as a precatalyst. Isolation of the [5 + 2] cycloaddition redox intermediates
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DOI: 10.1039/c9gc03992a
Abstract: A bioinspired organocatalytic cascade reaction mimicking both purpurogallin biosynthesis and copper amine oxidases (CuAOs) activity is described, at room temperature under ambient air, for the activation of the α-C–H bond of primary amines. The reaction… read more here.
Keywords: cycloaddition redox; primary amines; oxidative coupling; pyrogallol precatalyst ... See more keywords