Sign Up to like & get
recommendations!
0
Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c01565
Abstract: A formal (4 + 1)-cycloaddition of vinylcyclopropanes and Et2SiH2 to afford 3,4-disubstituted silolanes is reported. The reaction sequence commences with the known B(C6F5)3-catalyzed alkene hydrosilylation with dihydrosilanes. Cleavage of the remaining Si-H bond in the…
read more here.
Keywords:
c6f5 catalyzed;
catalyzed diastereoselective;
formal cycloaddition;
cycloaddition vinylcyclopropanes ... See more keywords