Synthesis and Studies of Bulky Cycloalkyl α,β-Dehydroamino Acids that Enhance Proteolytic Stability.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01962
Abstract: Three new bulky cycloalkyl α,β-dehydroamino acids (ΔAAs) have been designed and synthesized. Each residue enhances the rigidity of model peptides and their stability to proteolysis, with larger ring sizes exhibiting greater effects. Peptides containing bulky… read more here.
Keywords: cycloalkyl; bulky cycloalkyl; dehydroamino acids; proteolytic stability ... See more keywords
ortho-Cycloalkyl substituted N,N'-diaryliminoacenaphthene-Ni(ii) catalysts for polyethylene elastomers; exploring ring size and temperature effects.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt03362a
Abstract: A family of six unsymmetrical N,N'-diiminoacenaphthene-nickel(ii) bromide complexes, [1-{2,6-(Ph2CH)2-4-MeC6H2N}-2-(ArN)C2C10H6]NiBr2 (Ar = 2-(C6H11)-6-MeC6H2Ni1, 2-(C5H9)-6-MeC6H2Ni2, 2-(C8H15)-6-MeC6H2Ni3, 2-(C6H11)-4,6-Me2C6H2Ni4, 2-(C5H9)-4,6-Me2C6H2Ni5, 2-(C8H15)-4,6-Me2C6H2Ni6), each bearing one ring-size variable 4-R-2-methyl-6-cycloalkyl-substituted N-aryl group and one N'-4-methyl-2,6-dibenzhydrylphenyl group, have been prepared and fully characterized.… read more here.
Keywords: cycloalkyl substituted; ortho cycloalkyl; substituted diaryliminoacenaphthene; cycloalkyl ... See more keywords