Effects on the aromaticity and on the biradicaloid nature of acenes by the inclusion of a cyclobutadiene linkage
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DOI: 10.1007/s00214-020-02624-w
Abstract: Biphenylene is a well-characterized compound that includes the union of both aromatic and antiaromatic units: benzene and cyclobutadiene, respectively. In this work, we extend this structural theme to acene analogues with a cyclobutadiene linkage in… read more here.
Keywords: biradicaloid nature; cyclobutadiene; cyclobutadiene linkage; aromaticity biradicaloid ... See more keywords
Inverse-Sandwich Cyclobutadiene Dinickel Complexes: Synthesis and Structural Characterization
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DOI: 10.1246/bcsj.20200156
Abstract: Synthesis and structural characterization of inverse-sandwich complexes, whose planar conjugated ligand is a cyclobutadiene, have attracted much attention for their unique chemical bonding modes an... read more here.
Keywords: synthesis structural; structural characterization; cyclobutadiene; inverse sandwich ... See more keywords