Mn-catalyzed radical initiated domino transformation of alkynylated cyclohexadienones with TMSN3 and O2 to bicyclic azido alcohols.
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DOI: 10.1039/d0cc00102c
Abstract: An efficient Mn-catalyzed cascade azide radical addition/cyclization/oxygen insertion reaction of alkyne-tethered cyclohexadienones with TMSN3 under mild conditions is reported. This domino reaction presents good diastereoselectivity generating bicyclic azido alcohol scaffolds which can be transformed into… read more here.
Keywords: bicyclic azido; radical initiated; cyclohexadienones tmsn3; catalyzed radical ... See more keywords