Manganese porphyrins as efficient catalysts in solvent-free cyclohexane oxidation
Sign Up to like & getrecommendations! Published in 2017 at "Arabian Journal of Chemistry"
DOI: 10.1016/j.arabjc.2017.12.007
Abstract: Abstract Novel non-symmetric third-generation manganese metalloporphyrins, chlorido(5-(4-nitrophenyl)-10,15,20-triphenyl-2,3,7,8,12,13,17,18 octobromoporphyrinate)manganese(III) (MnBr8P1) and the mixture of isomers chlorido(5,10-(4-nitrophenyl)-15,20-diphenyl-2,3,7,8,12,13,17,18-octabromoporphyrinate)manganese(III) and chlorido(5,15-(4-nitrophenyl)-10,20-diphenyl-2,3,7,8,12,13,17,18-octabromoporphyrinate)manganese(III) (cis/trans-MnBr8P2) were obtained from their second-generation analogues (MnP1 and cis/trans-MnP2). These four catalysts were used in cyclohexane oxidation… read more here.
Keywords: cis trans; cyclohexane oxidation; generation; trans mnbr8p2 ... See more keywords
The role of nanoporous carbon materials in catalytic cyclohexane oxidation
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DOI: 10.1016/j.cattod.2019.07.036
Abstract: Abstract The C-scorpionate iron(II) complex [FeCl2(Tpm)] [Tpm = κ3−HC(C3H3N2)3] was immobilized on three nanoporous carbon supports to produce active, selective and recyclable catalysts for the oxidation of cyclohexane. The influence of the porous carbon supports… read more here.
Keywords: cyclohexane oxidation; cyclohexane; nanoporous carbon; carbon materials ... See more keywords
Cooperative behavior of perfluoro carboxylic acid on cyclohexane oxidation catalyzed by μ-nitrido diiron phthalocyanine complex
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DOI: 10.1016/j.jiec.2017.05.008
Abstract: Abstract μ-Nitrido diiron phthalocyanine complex has shown great performance in cyclohexane oxidation. Catalytic activity of μ-nitrido-bis[tetra(tert-butyl)phthalocyaninatoiron] complex could dramatically be enhanced in the presence of perfluoro carboxylic acid. Turnover number of cyclohexane oxidation reached 504,… read more here.
Keywords: nitrido diiron; perfluoro carboxylic; cyclohexane oxidation; carboxylic acid ... See more keywords