Palladium-catalyzed aerobic synthesis of ortho-substituted phenols from cyclohexanones and primary alcohols.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/c9cc09347h
Abstract: Due to the importance of phenols as structural cores and precursors of chemical products, synthesis of site-specific substituted phenols is highly desirable and a significant challenge. An aerobic palladium-catalyzed site-specific synthesis of ortho-substituted phenols from… read more here.
Keywords: cyclohexanones primary; substituted phenols; ortho substituted; primary alcohols ... See more keywords
Iodine (III)-Mediated Dehydroaromatization of Cyclohexanones with Primary Amines and CD3SSO3Na to Access ortho-SCD3 Anilines
Sign Up to like & getrecommendations! Published in 2023 at "Organic Chemistry Frontiers"
DOI: 10.1039/d3qo00481c
Abstract: Iodine (III)-mediated dehydroaromatization of cyclohexanones with primary amines and CD3SSO3Na has been developed, providing direct access ortho-SCD3 anilines with the formation of C-N and C-S bonds. Detailed mechanism studies indicates... read more here.
Keywords: dehydroaromatization cyclohexanones; mediated dehydroaromatization; iii mediated; iodine iii ... See more keywords