Ru–Zn/ZrO2 Nanocomposite Catalysts Fabricated by Galvanic Replacement for Benzene Partial Hydrogenation
Sign Up to like & getrecommendations! Published in 2018 at "ChemCatChem"
DOI: 10.1002/cctc.201701696
Abstract: A strategy based on galvanic replacement between metallic Zn and Ru salt followed by acid treatment was developed to fabricate supported Ru–Zn/ZrO2 nanocomposite catalysts with controlled contents of Zn for the benzene partial hydrogenation to… read more here.
Keywords: hydrogenation; partial hydrogenation; cyclohexene; benzene partial ... See more keywords
Mechanistic Understanding towards the Role of Cyclohexene in Enhancing the Efficiency of Manganese Porphyrin‐Catalyzed Aerobic Oxidation of Diphenylmethane
Sign Up to like & getrecommendations! Published in 2018 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201800317
Abstract: Efficiency enhanced by cyclohexene: the efficiency towards diphenylmethane oxidation, catalyzed by metalloporphyrins, is improved remarkably in the presence of cyclohexene. As a NAD(P)H‐like model, the roles of cyclohexene, promoting the initiation of a radical and… read more here.
Keywords: diphenylmethane; understanding towards; oxidation; mechanistic understanding ... See more keywords
Synthesis and characterization of an A2B2-type miktoarm star copolymer based on poly(ε-caprolactone) and poly(cyclohexene oxide)
Sign Up to like & getrecommendations! Published in 2018 at "Polymer Bulletin"
DOI: 10.1007/s00289-018-2396-9
Abstract: An A2B2-type miktoarm star copolymer with two linear poly(ε-caprolactone) (PCL) and two linear poly(cyclohexene oxide) (PCHO) arms was synthesized by using ring-opening polymerization (ROP), click chemistry, and photoinduced cationic polymerization, respectively. The ROP of ε-CL… read more here.
Keywords: type miktoarm; a2b2 type; star copolymer; pcl ... See more keywords
Highly Dispersed MnOx Nanoparticles on Shape-Controlled SiO2 Spheres for Ecofriendly Selective Allylic Oxidation of Cyclohexene
Sign Up to like & getrecommendations! Published in 2020 at "Catalysis Letters"
DOI: 10.1007/s10562-020-03205-z
Abstract: Shape-controlled metal nanomaterials are considered as a unique class of catalysts because of their synergistic size- and shape-dependent catalytic properties. This work reports the synthesis of a novel size- and shape-controlled catalyst, consisting of highly… read more here.
Keywords: shape controlled; oxidation; sio2; cyclohexene ... See more keywords
Hydrophilicity modification of MCM-41 with polyethylene glycol and supported ruthenium for benzene hydrogenation to cyclohexene
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Porous Materials"
DOI: 10.1007/s10934-018-0677-1
Abstract: Hydrophilic polyethylene glycol (PEG) modified MCM-41 and supported ruthenium catalyst were prepared, characterized and tested for benzene hydrogenation to cyclohexene. Ruthenium supported on PEG modified MCM-41 exhibits much better catalytic property than the unmodified catalyst.… read more here.
Keywords: benzene hydrogenation; supported ruthenium; mcm; polyethylene glycol ... See more keywords
Selective allylic oxidation of cyclohexene over a novel nanostructured CeO2–Sm2O3/SiO2 catalyst
Sign Up to like & getrecommendations! Published in 2018 at "Research on Chemical Intermediates"
DOI: 10.1007/s11164-018-3482-1
Abstract: Selective allylic oxidation of cyclohexene was investigated over nanostructured CeO2/SiO2 and CeO2–Sm2O3/SiO2 catalysts synthesized by a feasible deposition precipitation method. The CeO2–Sm2O3/SiO2 catalyst showed excellent catalytic efficiency with ~89 % cyclohexene conversion and ~90 % selectivity for… read more here.
Keywords: sm2o3 sio2; sio2; cyclohexene; oxidation cyclohexene ... See more keywords
Catalytic cyclohexene oxidation in the nano channels of a copper silicate material
Sign Up to like & getrecommendations! Published in 2019 at "Applied Catalysis A: General"
DOI: 10.1016/j.apcata.2019.01.019
Abstract: Abstract Herein we examined the catalytic activity of the copper silicate material SGU-29 for the aerobic partial oxidation of cyclohexene under mild conditions (1 bar of O2 at 70 °C). In particular, the catalytic properties of the… read more here.
Keywords: cyclohexene; oxidation; copper silicate; cyclohexene oxidation ... See more keywords
Increased selectivity for allylic oxidation of cyclohexene using TiO2 modified V2O5/MoO3 catalysts
Sign Up to like & getrecommendations! Published in 2017 at "Catalysis Communications"
DOI: 10.1016/j.catcom.2017.05.023
Abstract: V2O5 and MoO3 mixed oxides supported by SiO2 were studied as the catalysts in the aqueous phase allylic oxidation of cyclohexene to unsaturated alcohol 2-cyclohexene-1-ol and unsaturated ketone 2-cyclohexene-1-one. The additional layer of TiO2 deposited… read more here.
Keywords: cyclohexene; v2o5 moo3; oxidation cyclohexene; allylic oxidation ... See more keywords
Highly effective methylated Ti MCM-41 catalyst for cyclohexene oxidation
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DOI: 10.1016/j.materresbull.2018.03.017
Abstract: Abstract A series of Ti containing MCM-41 materials were synthesized with different Si/Ti molar ratios and tested for cyclohexene epoxidation reaction. TiMCM-41 with Si/Ti ratio 40 which gave maximum conversion and selectivity to epoxide was… read more here.
Keywords: effective methylated; mcm catalyst; highly effective; spectroscopy ... See more keywords
Oxy-functionalization of olefins with neat and heterogenized binuclear V(IV)O and Fe(II) complexes: Effect of steric hindrance on product selectivity and output in homogeneous and heterogeneous phase
Sign Up to like & getrecommendations! Published in 2019 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2019.110424
Abstract: Abstract Neat {[VO(sal2bz)]2; [Fe(sal2bz)(H2O)2]2·2H2O} and zeolite-Y immobilized {[VO(sal2bz)]2-Y; [Fe(sal2bz)(H2O)2]2-Y} binuclear complexes have been prepared and characterized by spectroscopic techniques (IR, UV–vis), elemental analyses (CHN, ICP-OES), thermal study (TGA), scanning electron micrograph (SEM), adsorption study (BET)… read more here.
Keywords: steric hindrance; oxidation; binuclear complexes; cyclohexene ... See more keywords
Synthesis, characterization and reactivity of halides/pseudohalides and their complexes containing ruthenium II in the hydrogenation of cyclohexene
Sign Up to like & getrecommendations! Published in 2017 at "Polyhedron"
DOI: 10.1016/j.poly.2017.08.013
Abstract: Abstract In this paper, the influence of pseudohalide ligands coordinated to the ruthenium center on the hydrogenation of cyclohexene was investigated. The pseudohalide complexes containing ruthenium were synthesized from the cis-[RuCl2(dppb)(N-N)] {where N-N = 2,2′-bipyridine (bipy) (1A),… read more here.
Keywords: cis; ruthenium; dppb; bipy ... See more keywords