Chiral Cyclohexyl-Fused Spirobiindanes: Practical Synthesis, Ligand Development, and Asymmetric Catalysis.
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DOI: 10.1021/jacs.8b07125
Abstract: 1,1'-Spirobiindane has been one type of privileged skeleton for chiral ligand design, and 1,1'-spirobiindane-based chiral ligands have demonstrated outstanding performance in various asymmetric catalysis. However, the access to enantiopure spirobiindane is quite tedious, which obstructs… read more here.
Keywords: cyclohexyl; cyclohexyl fused; spirobiindane; ligand ... See more keywords
The beneficial effect of cyclohexyl substituent on the in vitro anticancer activity of diiron vinyliminium complexes.
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DOI: 10.1039/d3dt00186e
Abstract: Novel diiron vinyliminium complexes, [Fe2Cp2(CO)(μ-CO){μ-η1:η3-C(R3)CHCNMe(R2)}]CF3SO3 (2a-f; R2 = 4-C6H4OMe, Cy or Me; R3 = Cy, CH2Cy or 4-C6H4OMe; Cy = cyclohexyl, Cp = η5-C5H5), were synthesized by alkyne insertion reaction from the corresponding diiron aminocarbyne… read more here.
Keywords: vinyliminium; cyclohexyl; activity; vinyliminium complexes ... See more keywords
In vitro and in vivo antimelanoma effect of ethyl ester cyclohexyl analog of ethylenediamine dipropanoic acid
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DOI: 10.1097/cmr.0000000000000409
Abstract: Melanoma, an aggressive skin tumor with high metastatic potential, is associated with high mortality and increasing morbidity. Multiple available chemotherapeutic and immunotherapeutic modalities failed to improve survival in advanced disease, and the search for new… read more here.
Keywords: melanoma; cyclohexyl; apoptosis; antimelanoma ... See more keywords
Toxicity Study and Binding Analysis of Newly Synthesized Antifungal N-(4-aryl/cyclohexyl)-2-(pyridine-4-yl carbonyl) hydrazinecarbothioamide Derivative with Bovine Serum Albumin
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DOI: 10.3390/ijms24054942
Abstract: The presence of the p-aryl/cyclohexyl ring in the N-(4-aryl/cyclohexyl)-2-(pyridine-4-yl carbonyl) hydrazine carbothioamide derivative (2C) is reported to enhance the antifungal properties when compared to those of itraconazole. Serum albumins present in plasma bind and transport… read more here.
Keywords: aryl cyclohexyl; cyclohexyl; cyclohexyl pyridine; pyridine carbonyl ... See more keywords
Non-Coplanar Diphenyl Fluorene and Weakly Polarized Cyclohexyl Can Effectively Improve the Solubility and Reduce the Dielectric Constant of Poly (Aryl Ether Ketone) Resin
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DOI: 10.3390/polym15040962
Abstract: With the rapid development of high-frequency communication and large-scale integrated circuits, insulating dielectric materials require a low dielectric constant and dielectric loss. Poly (aryl ether ketone) resins (PAEK) have garnered considerable attention as an intriguing… read more here.
Keywords: poly aryl; cyclohexyl; aryl ether; dielectric constant ... See more keywords