Highly Enantioselective Rhodium(I)-Catalyzed Alder-ene-type Cycloisomerization of 1,7-Enynes.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.1c04171
Abstract: The transition-metal-catalyzed asymmetric cycloisomerization of 1,7-enynes is regarded as a formidable challenge due to the poor ability of 1,7-enynes to serve as bidentate ligands to metal. In this Letter, a highly enantioselective rhodium(I)-catalyzed Alder-ene-type cycloisomerization… read more here.
Keywords: cycloisomerization enynes; enantioselective rhodium; catalyzed alder; cycloisomerization ... See more keywords
Palladium-catalyzed divergent cycloisomerization of 1,6-enynes controlled by functional groups for the synthesis of pyrroles, cyclopentenes, and tetrahydropyridines
Sign Up to like & getrecommendations! Published in 2021 at "Organic Chemistry Frontiers"
DOI: 10.1039/d1qo00581b
Abstract: A palladium-catalyzed divergent cycloisomerization of 1,6-enynes controlled by functional groups was developed, leading to functionalized pyrroles, cyclopentenes, and tetrahydropyridines. read more here.
Keywords: catalyzed divergent; controlled functional; enynes controlled; palladium catalyzed ... See more keywords