Cytotoxic performances of new anionic cyclometalated Pt(II) complexes bearing chelated O^O ligands
Sign Up to like & getrecommendations! Published in 2020 at "Applied Organometallic Chemistry"
DOI: 10.1002/aoc.5455
Abstract: Andreea Ionescu,* Rossella Caligiuri, Nicolas Godbert, Loredana Ricciardi, Massimo La Deda, Mauro Ghedini, Nicola Ferri, Maria Giovanna Lupo, Giorgio Facchetti, Isabella Rimoldi , Iolinda Aiello* a. MAT-InLAB, LASCAMM CR-INSTM, Unità INSTM della Calabria,Dipartimento di Chimica… read more here.
Keywords: new anionic; anionic cyclometalated; cyclometalated complexes; performances new ... See more keywords
Phosphorescent Tris-cyclometalated Pt(IV) Complexes with Mesoionic N-Heterocyclic Carbene and 2-Arylpyridine Ligands
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c02039
Abstract: The synthesis, structure, photophysical properties, and electrochemistry of the first series of Pt(IV) tris-chelates bearing cyclometalated aryl-NHC ligands are reported. The complexes have the general formula [Pt(trz)2(C∧N)]+, combining two units of the cyclometalated, mesoionic aryl-NHC… read more here.
Keywords: mesoionic heterocyclic; phosphorescent tris; complexes mesoionic; tris cyclometalated ... See more keywords
Synthesis, Structures, and Reactivity of Single and Double Cyclometalated Complexes Formed by Reactions of [Cp*MCl2]2 (M = Ir and Rh) with Dinaphthyl Phosphines
Sign Up to like & getrecommendations! Published in 2018 at "ACS Omega"
DOI: 10.1021/acsomega.8b00193
Abstract: Reactions of two dinaphthyl phosphines with [Cp*IrCl2]2 have been carried out. In the case of di(α-naphthyl)phenylphosphine (1a), a simple P-coordinated neutral adduct 2a is obtained. However, tert-butyldi(α-naphthyl)phenylphosphine (1b) is cyclometalated to form [Cp*IrCl(P^C)] (3b). Complexes… read more here.
Keywords: synthesis structures; structures reactivity; cyclometalated complexes; double cyclometalated ... See more keywords
(P,C)-cyclometalated complexes derived from naphthyl phosphines: versatile and powerful tools in organometallic chemistry.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical Society reviews"
DOI: 10.1039/d2cs00564f
Abstract: The chemistry of (P,C)-cyclometalated complexes derived from naphthyl phosphines [Np(P,C)M] is presented and analysed in this review. The three main synthetic approaches, namely P-chelation assisted C-H activation, oxidative addition and transmetalation, are described and compared.… read more here.
Keywords: naphthyl phosphines; chemistry cyclometalated; chemistry; cyclometalated complexes ... See more keywords