Synthesis, structures and catalytic activity of cyclometalated rhenium complexes
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DOI: 10.1039/c6ra28263f
Abstract: Thermal reactions of aryl-substituted phosphines or phosphinites with Re2(CO)10 in chlorobenzene resulted in the corresponding five-membered cyclometalated rhenium complexes (1–5) via an intramolecular activation of the C(sp2)–H or C(sp3)–H bond. The only exception occurred in… read more here.
Keywords: rhenium complexes; structures catalytic; synthesis structures; bond ... See more keywords