Cyclometalated Spirobifluorene Imidazolylidene Platinum(II) Complexes with Predominant 3LC Emissive Character and High Photoluminescence Quantum Yields.
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DOI: 10.1021/acs.inorgchem.2c02141
Abstract: Two novel bidentate C^C*spiro cyclometalated platinum(II) complexes comprising a spiro-conjugated bifluorene ligand and different β-diketonate auxiliary ligands are synthesized and characterized. Their preparation employs a robust and elaborate synthetic protocol commencing with an N-heterocyclic carbene… read more here.
Keywords: platinum complexes; cyclometalated spirobifluorene; spirobifluorene imidazolylidene; quantum yields ... See more keywords