Mechanistic Studies on Ruthenium(II)-Catalyzed Base-Free Transfer Hydrogenation Triggered by Roll-Over Cyclometalation.
Sign Up to like & getrecommendations! Published in 2017 at "ChemPlusChem"
DOI: 10.1002/cplu.201600526
Abstract: The synthesis of 2-substituted pyridine-pyrimidine ligands and their complexation with arene ruthenium(II) chloride moieties is reported. Depending on the electronic and steric influences of the ligand, the catalysts undergo CH activation by roll-over cyclometalation. This… read more here.
Keywords: cyclometalation; base free; transfer hydrogenation; roll cyclometalation ... See more keywords
One-Pot Synthesis of Acetylacetonate-Based Isomeric Phosphorescent Cyclometalated Iridium(III) Complexes via Random Cyclometalation: A Strategy for Excited-State Manipulation.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03597
Abstract: The excited-state manipulation of the phosphorescent iridium(III) complexes plays a vital role in their photofunctional applications. The development of the molecular design strategy promotes the creative findings of novel iridium(III) complexes. The current molecular design… read more here.
Keywords: iridium iii; iii complexes; cyclometalation; strategy ... See more keywords
Secondary Coordination Sphere Alkylation Promotes Cyclometalation.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00427
Abstract: Diphosphines have taken on a dominant role as supporting ligands in transition-metal chemistry. Here, we describe complexes of the type [Cp*Fe(diphosphine)(X)] (X = Cl, H) where for diphosphine = 1,2-bis(di-allylphosphino)ethane (tape), a Lewis-acidic secondary coordination… read more here.
Keywords: secondary coordination; chemistry; coordination sphere; cyclometalation ... See more keywords
Synthesis of substituted (N,C) and (N,C,C) Au(III) complexes: the influence of sterics and electronics on cyclometalation reactions.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00371f
Abstract: Cyclometalated Au(III) complexes are of interest due to their catalytic, medicinal, and photophysical properties. Herein, we describe the synthesis of derivatives of the type (N,C)Au(OAcF)2 (OAcF = trifluoroacetate) and (N,C,C)AuOAcF by a cyclometalation route, where… read more here.
Keywords: iii complexes; influence; synthesis substituted; iii ... See more keywords