Chasing the agostic interaction in ligand assisted cyclometallation reactions of palladium(ii).
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DOI: 10.1039/c7dt03525j
Abstract: A 500 MHz NMR study of the reaction between 1-tetralone oxime and PdCl42- in CD3OD shows resonances attributable to a potential agostic intermediate prior to the formation of the insoluble cyclopalladated product which itself was… read more here.
Keywords: ligand assisted; assisted cyclometallation; interaction ligand; cyclometallation reactions ... See more keywords