Structural elucidation of liquid cyclooctatetraene and cyclooctadienes in inclusion crystals
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2020.128775
Abstract: Abstract A disubstituted adamantane derivative having chloropyrimidine units (1) was utilized as a V-shaped host molecule to create inclusion crystals and to elucidate the molecular structures of the guests by X-ray crystallographic analysis. The crystallization… read more here.
Keywords: cyclooctatetraene; structural elucidation; host; inclusion crystals ... See more keywords
The dinuclear scandium(III) cyclooctatetraenyl chloride complex di-μ-chlorido-bis[(η8-cyclooctatetraene)(tetrahydrofuran-κO)scandium(III)].
Sign Up to like & getrecommendations! Published in 2017 at "Acta crystallographica. Section C, Structural chemistry"
DOI: 10.1107/s2053229617005678
Abstract: Only a few cyclooctatetraene dianion (COT) π-complexes of lanthanides have been crystallographically characterized. This first single-crystal X-ray diffraction characterization of a scandium(III) COT chloride complex, namely di-μ-chlorido-bis[(η8-cyclooctatetraene)(tetrahydrofuran-κO)scandium(III)], [Sc2(C8H8)2Cl2(C4H8O)2] or [Sc(COT)Cl(THF)]2 (THF is tetrahydrofuran), (1), reveals… read more here.
Keywords: cyclooctatetraene; scandium iii; cot; scandium ... See more keywords