Chiral (cyclopentadienone)iron complexes with a stereogenic plane as pre-catalysts for the asymmetric hydrogenation of polar double bonds
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron"
DOI: 10.1016/j.tet.2019.01.057
Abstract: Abstract In this paper, we describe a small library of easy-to-prepare chiral (cyclopentadienone)iron pre-catalysts for enantioselective C O and C N hydrogenations. Starting from readily accessible achiral materials, six chiral (cyclopentadienone)iron complexes (1a-f) possessing a… read more here.
Keywords: pre catalysts; chiral cyclopentadienone; cyclopentadienone iron;
Zwitterionic Halido Cyclopentadienone Iron Complexes and Their Catalytic Performance in Hydrogenation Reactions.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c04298
Abstract: The zwitterionic halido cyclopentadienone iron complexes FeX(CO)2-NMe3 (X = Cl, Br, I) were prepared and characterized by NMR, XRD, MS, IR, and elemental analysis. Their catalytic performance in hydrogenation and transfer hydrogenation was assessed. Transfer… read more here.
Keywords: halido cyclopentadienone; hydrogenation; chemistry; hydrogenation reactions ... See more keywords
Cyclopentadienone Iron Tricarbonyl Complexes-Catalyzed Hydrogen Transfer in Water
Sign Up to like & getrecommendations! Published in 2020 at "Molecules"
DOI: 10.3390/molecules25020421
Abstract: The development of efficient and low-cost catalytic systems is important for the replacement of robust noble metal complexes. The synthesis and application of a stable, phosphine-free, water-soluble cyclopentadienone iron tricarbonyl complex in the reduction of… read more here.
Keywords: water; iron tricarbonyl; iron; cyclopentadienone iron ... See more keywords