Distinctive Stereochemically Linked Cooperative Effects in Bimetallic Titanium Olefin Polymerization Catalysts
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DOI: 10.1021/acs.organomet.7b00641
Abstract: The complex (μ-Me2C-3,3′){(η5-cyclopentadienyl)[1-Me2Si-(tBuN)](TiMe2)}2 (3) was prepared as a new binuclear catalyst motif for homogeneous olefin polymerization. Complex 3 exists as rac-3 and meso-3 diastereomers, which can be separated and characterized by solution NMR spectroscopy and… read more here.
Keywords: olefin polymerization; cyclopentadienyl me2si; spectroscopy; rac ... See more keywords