Cyclopentadienyl molybdenum(II) compounds bearing carboxylic acid functional group
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DOI: 10.1016/j.ica.2018.04.032
Abstract: Abstract This work describes a procedure giving cyclopentadienyl molybdenum(II) compounds bearing carboxylic acid function group. It involves synthesis of carboxylic acid ester functionalized cyclopentadienides, their coordination to molybdenum(II) precursor and saponification of ester function groups.… read more here.
Keywords: compounds bearing; cyclopentadienyl molybdenum; group; carboxylic acid ... See more keywords
Synthesis and catalytic reactivity in Friedel–Crafts acylations of monobridged bis(cyclopentadienyl)molybdenum(I) carbonyl complexes
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DOI: 10.1016/j.poly.2018.03.021
Abstract: Abstract When the monobridged biscyclopentadienes (C5H5)R(C5H5) [R = C(CH3)2 (1), Si(CH3)2 (2), C(CH2)5 (3)] reacted with Mo(CO)6 in refluxing xylene, the corresponding complexes [(η5-C5H4)2R][Mo(CO)3]2 [R = C(CH3)2 (4), Si(CH3)2 (5), C(CH2)5 (6)] were obtained. These complexes were separated by… read more here.
Keywords: molybdenum carbonyl; cyclopentadienyl molybdenum; bis cyclopentadienyl; carbonyl complexes ... See more keywords