Cyclopentadienyl-ruthenium(II) complexes as efficient catalysts for the reduction of carbonyl compounds
Sign Up to like & getrecommendations! Published in 2017 at "Tetrahedron"
DOI: 10.1016/j.tet.2017.01.067
Abstract: Abstract This work reports the reduction of a large variety of aldehydes and ketones with the system PhSiH3/[CpRu(PPh3)2Cl] in good to excellent yields and high chemoselectivity. The catalyst [CpRu(PPh3)2Cl] can be used in at least… read more here.
Keywords: reduction; catalysts reduction; complexes efficient; ruthenium complexes ... See more keywords
Parent Cyclopentadienyl Ruthenium(II) Chloride Synthon: Derivatization to CpRu Amido, Imido, and Oxo Complexes
Sign Up to like & getrecommendations! Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.9b00576
Abstract: The complex salt [CpRu(η6-C10H8)][(CpRu)2(μ-Cl)3] ([1][2]) was synthesized and found to be a useful CpRuCl synthon. The ions [1]+ and [2]− cleanly comproportionate into monomeric CpRuCl(L)2 complex... read more here.
Keywords: ruthenium chloride; synthon; chloride synthon; parent cyclopentadienyl ... See more keywords