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Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.3c01326
Abstract: Unprecedented types of metal-free complete o-phenylene bridged N4-cyclophanes (M1 and M2) have been synthesized via sequential palladium-catalyzed Buchwald-Hartwig N-arylation reactions. These cyclophanes may be considered as aromatic analogues of aliphatic group-spaced N4-macrocycles. These have been…
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Keywords:
cyclophane missing;
completely phenylene;
phenylene bridged;
cyclophane ... See more keywords