Gold-catalysed rearrangement of unconventional cyclopropane-tethered 1,5-enynes.
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DOI: 10.1039/d2cc02869g
Abstract: The synthesis of particular cyclopropane-tethered 1,5-enynes, namely 6-alkynyl-4-alkylidenebicyclo[3.1.0]hex-2-enes, enabled the discovery of unprecedented gold-catalyzed rearrangment to indenes. A computational study of the mechanism of this profound skeleton rearrangement is also disclosed. read more here.
Keywords: catalysed rearrangement; tethered enynes; gold catalysed; cyclopropane tethered ... See more keywords