Ni-Catalyzed β-Alkylation of Cyclopropanol-Derived Homoenolates.
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DOI: 10.1021/acs.orglett.9b03435
Abstract: Metal homoenolates are valuable synthetic intermediates which provide access to β-functionalized ketones. In this report, we disclose a Ni-catalyzed β-alkylation reaction of cyclopropanol-derived homoenolates using redox-active N-hydroxyphthalimide (NHPI) esters as the alkylating reagents. The reaction… read more here.
Keywords: cyclopropanol; cyclopropanol derived; derived homoenolates; catalyzed alkylation ... See more keywords