Catalytic Synthesis of Cyclopropenium Cations with Rh-Carbynoids
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DOI: 10.1021/jacs.2c07769
Abstract: Herein, we report the first catalytic one-step synthesis of cyclopropenium cations (CPCs) with readily available alkynes and hypervalent iodine reagents as carbyne sources. Key to the process is the catalytic generation of a novel Rh-carbynoid… read more here.
Keywords: synthesis cyclopropenium; cyclopropenium cations; synthesis; catalytic synthesis ... See more keywords