M-CPOnes: transition metal complexes with cyclopropenone-based ligands for light-triggered carbon monoxide release.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00835a
Abstract: A new class of CO-releasing molecules, M-CPOnes, was prepared combining cyclopropenone-based ligands for CO release with the modular scaffold of transition metal complexes. In proof-of-concept studies, M-CPOnes based on ZnII, FeII and CoII are stable… read more here.
Keywords: spectroscopy; based ligands; cyclopropenone; release ... See more keywords
Density Functional Theory Analysis of the Copolymerization of Cyclopropenone with Ethylene Using a Palladium Catalyst
Sign Up to like & getrecommendations! Published in 2022 at "Polymers"
DOI: 10.3390/polym14235273
Abstract: Density functional theory has been used to elucidate the mechanism of Pd copolymerization of cyclopropenone with ethylene. The results reveal that introducing ethylene and cyclopropenone to Pd catalyst is thermodynamically feasible and generates the α,β-unsaturated… read more here.
Keywords: functional theory; catalyst; ethylene; cyclopropenone ... See more keywords