Pd-Catalyzed Synthesis of Densely Functionalized Cyclopropyl Vinyl Sulfides Reveals the Origin of High Selectivity in a Fundamental Alkyne Insertion Step
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DOI: 10.1021/acscatal.0c02053
Abstract: Catalytic atom-economic hydrothiolation of cyclopropyl acetylenes was developed. Using Pd/NHC complex as a precatalyst, regioselective addition of thiols to cyclopropyl acetylenes was successfully ... read more here.
Keywords: densely functionalized; synthesis densely; cyclopropyl; functionalized cyclopropyl ... See more keywords