Ring-opening fluorination of cyclopropylmethanols and cycloprpanecarbardehydes with diethylaminosulfur trifluoride
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DOI: 10.1016/j.tetlet.2020.152655
Abstract: Abstract The reaction of cyclopropylmethanols bearing aromatic substituents on their cyclopropane rings with diethylaminosulfur trifluoride (DAST) effectively caused ring-opening fluorination to produce homoallylic fluorides. This reaction proceeded via a carbocation intermediate. DAST reacted with cyclopropanecarbaldehydes… read more here.
Keywords: ring opening; fluorination cyclopropylmethanols; diethylaminosulfur trifluoride; cyclopropylmethanols cycloprpanecarbardehydes ... See more keywords