Novel pyrene-BODIPY dyes based on cyclotriphosphazene scaffolds: Synthesis, photophysical and spectroelectrochemical properties
Sign Up to like & getrecommendations! Published in 2019 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2019.05.022
Abstract: Abstract Two novel cyclotriphosphazene compounds (Cpz-2, 3) bearing mono- and distyryl(pyrene) borondipyrromethene (BODIPY) dyes (Bod-4, 5) were synthesized and characterized by using elemental analysis, FT-IR, MALDI-TOF, 1H NMR, 13C NMR and 31P NMR techniques. The… read more here.
Keywords: pyrene bodipy; cyclotriphosphazene; novel pyrene; properties novel ... See more keywords
Formation of a copper–copper bond in coordination of a cyclotriphosphazene ligand toward Cu(II): Structural, spectral and docking studies
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2020.127804
Abstract: Abstract Two cyclotriphosphazene compounds, [HMPAP]2[SO4]·2CH3OH (1), MPAP: 2,2,4,4,6,6-hexakis(2-methyl-1λ4-pyridin-1-yl)-1,3,5,2λ5,4λ5,6λ5-triazatriphosphinine and [Cu(μ-OAc)2(MPAP)]2 (2), were prepared and identified by elemental analysis, FT-IR, Raman spectroscopy and single-crystal X-ray diffraction. In the crystal structure of 1, one nitrogen atom of… read more here.
Keywords: ligand toward; cyclotriphosphazene; bond; docking studies ... See more keywords
Mercury(II) coordination polymers based on aniline-substituted tetra pyridyloxy cyclotriphosphazene: Syntheses, characterizations and UV–Vis absorption properties
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.114138
Abstract: Abstract Dianiline-tetrapyridyloxy-cyclotriphosphazene (AnPyCp), as a novel flexible molecular building block, and its mercury(II) coordination polymers were successfully synthesized. The isolated crystalline coordination polymers, formulated as {[Hg(AnPyCp)(Cl)2]·CH3CN}n (1) and {[Hg2(AnPyCp)(I)4]·CH3CN}n (2), were structurally characterized by elemental… read more here.
Keywords: coordination; cyclotriphosphazene; analysis; mercury coordination ... See more keywords
Enhanced flame retardancy of DGEBA epoxy resin with a novel bisphenol-A bridged cyclotriphosphazene
Sign Up to like & getrecommendations! Published in 2017 at "Polymer Degradation and Stability"
DOI: 10.1016/j.polymdegradstab.2017.08.027
Abstract: Abstract A novel flame retardant, namely bisphenol-A bridged penta(phenoxy)cyclotriphosphazene (A-BP), was synthesized and characterized successfully. Obtained A-BP was mixed in different proportions with diglycidyl ether of bisphenol-A (DGEBA) in order to prepare a series of… read more here.
Keywords: flame retardant; cyclotriphosphazene; enhanced flame; bisphenol bridged ... See more keywords
The synthesis, curing kinetics, thermal properties and flame rertardancy of cyclotriphosphazene-containing multifunctional epoxy resin
Sign Up to like & getrecommendations! Published in 2019 at "Thermochimica Acta"
DOI: 10.1016/j.tca.2019.178348
Abstract: Abstract The cyclotriphosphazene-based multi-functional epoxy resin hexa-[4-(glycidyloxymethyl)phenoxy]-cyclotriphosphazene (HGPCP) was designed and synthesized from commercial available hexachlorocyclotriphosphazene (HCCP). The chemical structure of HGPCP was characterized by fourier transform infrared (FTIR) spectroscopy, 1H, 13C and 31P NMR… read more here.
Keywords: epoxy resin; ddm; hgpcp; cyclotriphosphazene ... See more keywords
Sustainable and tough polyurethane films with self-healability and flame retardance enabled by reversible chemistry and cyclotriphosphazene
Sign Up to like & getrecommendations! Published in 2019 at "Polymer Chemistry"
DOI: 10.1039/c9py00680j
Abstract: Broadly applied polyurethane (PU) films are required to be self-healing, flame-retardant, recyclable, mechanically reinforced, etc., but integrating these ideal properties into a single system is a huge challenge. On the basis of reversible Diels–Alder (DA)… read more here.
Keywords: cyclotriphosphazene; flame retardance; chemistry; polyurethane ... See more keywords
The elusive cyclotriphosphazene molecule and its Dewar benzene–type valence isomer (P3N3)
Sign Up to like & getrecommendations! Published in 2020 at "Science Advances"
DOI: 10.1126/sciadv.aba6934
Abstract: Cyclotriphosphazene (P3N3) and its Dewar benzene–type isomer were identified on the basis of their photochemical properties. Although the chemistry of phosphorus and nitrogen has fascinated chemists for more than 350 years, the Hückel aromatic cyclotriphosphazene… read more here.
Keywords: cyclotriphosphazene; isomer; benzene type; chemistry ... See more keywords
Synthesis, characterization, thermal and fire retardant properties of new homo- and block copolymers of polyacrylate and epoxy resin with cyclotriphosphazene core
Sign Up to like & getrecommendations! Published in 2019 at "Polimery"
DOI: 10.14314/polimery.2019.9.2
Abstract: New homoand block copolymers composed of polyacrylate and epoxy resin with hexafunctional cyclotriphosphazene core were synthesized and characterized by FT-IR and 1H-, 13C-, and 31PNMR. The first homopolymer, PN-polyacry was prepared from the direct condensation… read more here.
Keywords: epoxy resin; polyacrylate epoxy; cyclotriphosphazene; block copolymers ... See more keywords