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Published in 2025 at "ChemSusChem"
DOI: 10.1002/cssc.202501352
Abstract: Polyethylene terephthalate (PET) is a versatile, relatively low-cost thermoplastic polymer, but its nonbiodegradability and extensive use lead to significant accumulation and environmental risks. The main roadblocks of current plastic recycling technologies include low-quality recycled plastics…
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Keywords:
cyrene;
pet;
polyethylene terephthalate;
dihydrolevoglucosenone cyrene ... See more keywords
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Published in 2020 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2020.110813
Abstract: Abstract An emerging biogenic aprotic solvent is the cellulose-derived dihydrolevoglucosenone, or 6,8-dioxabicyclooctanone (Cyrene™). This paper explores the use of Cyrene in lipase-catalyzed biotransformations, both in aqueous solutions – as co-solvent – as well as non-conventional…
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Keywords:
assessing biocatalysis;
using dihydrolevoglucosenone;
dihydrolevoglucosenone cyrene;
biocatalysis ... See more keywords
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Published in 2017 at "Green Chemistry"
DOI: 10.1039/c7gc00908a
Abstract: Cyrene as a bio-alternative solvent: a highly efficient, waste minimizing protocol for the synthesis of ureas from isocyanates and secondary amines in the bio-available solvent Cyrene is reported. This method eliminated the use of toxic…
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Keywords:
synthesis ureas;
alternative solvent;
cyrene;
solvent cyrene ... See more keywords
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Published in 2020 at "Polymer Chemistry"
DOI: 10.1039/d0py01471k
Abstract: The levoglucosenone-based norbornenes family was extended to include a new bi-functional methacrylate monomer that, upon ROMP in Cyrene™, leads to polymers with pendent methacrylate moieties which can be modified by post-polymerization reactions.
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Keywords:
polymerization;
chemo enzymatic;
enzymatic synthesis;
cyrene ... See more keywords
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Published in 2024 at "Chemical communications"
DOI: 10.1039/d4cc04571h
Abstract: Reversible addition fragmentation chain transfer (RAFT) solution polymerisation of the bio-based lactone monomer γ-methyl-α-methylene-γ-butyrolactone (γMeMBL) has been demonstrated in DMSO and Cyrene. RAFT control was evidenced by control over molecular weights, low disperisites, and kinetic…
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Keywords:
cyrene;
raft solution;
solution polymerisation;
polymerisation ... See more keywords