Articles with "cyrene" as a keyword



Efficient Recovery and Fast Hydrolysis of Polyethylene Terephthalate by Dihydrolevoglucosenone (Cyrene).

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Published in 2025 at "ChemSusChem"

DOI: 10.1002/cssc.202501352

Abstract: Polyethylene terephthalate (PET) is a versatile, relatively low-cost thermoplastic polymer, but its nonbiodegradability and extensive use lead to significant accumulation and environmental risks. The main roadblocks of current plastic recycling technologies include low-quality recycled plastics… read more here.

Keywords: cyrene; pet; polyethylene terephthalate; dihydrolevoglucosenone cyrene ... See more keywords

Assessing biocatalysis using dihydrolevoglucosenone (Cyrene™) as versatile bio-based (co)solvent

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Published in 2020 at "Molecular Catalysis"

DOI: 10.1016/j.mcat.2020.110813

Abstract: Abstract An emerging biogenic aprotic solvent is the cellulose-derived dihydrolevoglucosenone, or 6,8-dioxabicyclooctanone (Cyrene™). This paper explores the use of Cyrene in lipase-catalyzed biotransformations, both in aqueous solutions – as co-solvent – as well as non-conventional… read more here.

Keywords: assessing biocatalysis; using dihydrolevoglucosenone; dihydrolevoglucosenone cyrene; biocatalysis ... See more keywords

Synthesis of ureas in the bio-alternative solvent Cyrene

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Published in 2017 at "Green Chemistry"

DOI: 10.1039/c7gc00908a

Abstract: Cyrene as a bio-alternative solvent: a highly efficient, waste minimizing protocol for the synthesis of ureas from isocyanates and secondary amines in the bio-available solvent Cyrene is reported. This method eliminated the use of toxic… read more here.

Keywords: synthesis ureas; alternative solvent; cyrene; solvent cyrene ... See more keywords

Chemo-enzymatic synthesis of a levoglucosenone-derived bi-functional monomer and its ring-opening metathesis polymerization in the green solvent Cyrene™

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Published in 2020 at "Polymer Chemistry"

DOI: 10.1039/d0py01471k

Abstract: The levoglucosenone-based norbornenes family was extended to include a new bi-functional methacrylate monomer that, upon ROMP in Cyrene™, leads to polymers with pendent methacrylate moieties which can be modified by post-polymerization reactions. read more here.

Keywords: polymerization; chemo enzymatic; enzymatic synthesis; cyrene ... See more keywords

RAFT solution polymerisation of bio-based γ-methyl-α-methylene-γ-butyrolactone monomer in DMSO and Cyrene.

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Published in 2024 at "Chemical communications"

DOI: 10.1039/d4cc04571h

Abstract: Reversible addition fragmentation chain transfer (RAFT) solution polymerisation of the bio-based lactone monomer γ-methyl-α-methylene-γ-butyrolactone (γMeMBL) has been demonstrated in DMSO and Cyrene. RAFT control was evidenced by control over molecular weights, low disperisites, and kinetic… read more here.

Keywords: cyrene; raft solution; solution polymerisation; polymerisation ... See more keywords