3D coordination polymers constructed from d10 metal ions, flexible 1,2,4-triazole derivatives and aromatic tetracarboxylates: Syntheses, structures, thermal and luminescent properties
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Solid State Chemistry"
DOI: 10.1016/j.jssc.2021.122011
Abstract: Abstract The reaction of mixed-ligands 1,2,4,5-benzene tetracarboxylic acid (H4btec) and 1,2-bis(4-amino-5-methylmercapto-1,2,4-triazole-3-yl)ethane (bamte) with zinc(II) nitrate hexahydrate under hydrothermal conditions led to the formation of the coordination polymer [Zn2 (bamte) (btec)]n (CP1), whereas the reaction of… read more here.
Keywords: metal ions; coordination; constructed d10; coordination polymers ... See more keywords
Synthesis and characterization of d10 metal complexes of 3-Me-5-FcPz: Structural, theoretical and third order nonlinear optical properties
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2016.08.036
Abstract: Abstract The d10 metal complexes based on 3-methyl-5-ferrocenyl-1H-pyrazole (L = 3-Me-5-FcPz) ligand [M(L)4(NO3)2] Zn=(1) and Cd=(2), [Hg(L)4(NO3)2].dmf (3) have been synthesized and characterized by FT-IR, NMR, UV–Vis and elemental analysis. The molecular structure of compound 2 and… read more here.
Keywords: d10 metal; order; third order; metal complexes ... See more keywords
First-Principles Calculations on Narrow-Band Gap d10 Metal Oxides for Photocatalytic H2 Production: Role of Unusual In2+ Cations in Band Engineering.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00859
Abstract: The d10 metal oxides with low effective mass and high mobility of photoexcited electrons have received much attention in photocatalytic water splitting. However, there are still challenges in practical application due to insufficient visible light… read more here.
Keywords: metal oxides; band gap; d10 metal; narrow band ... See more keywords
On solvated tin(iv) ions and the coordination chemistry of high-valent d10 metal ions.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt01097a
Abstract: A very slow oxidation of dimethylsulfoxide (dmso) solvated tin(ii) ions in solution results in the formation of a crystalline, structurally determined compound, [CH3Sn(OS(CH3)2)5](ClO4)3, whereas a similar reaction in N,N-dimethylthioformamide (dmtf) forms a crystalline solid with… read more here.
Keywords: d10 metal; chemistry; solvated tin; tin ions ... See more keywords